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5 Common Ammonia Nitrogen Removal Agents Compared

2025-05-23

氨氮去除剂的作用及不同类型的应用场景

With increasingly stringent environmental regulations, ammonia nitrogen removal from wastewater has become a critical challenge in water treatment. As the core chemical treatment agents, the proper selection and use of ammonia nitrogen removal agents directly impact treatment effectiveness and costs. This article systematically explains the working mechanisms, main types, and key application considerations of these agents in various scenarios.

 

1. Core Functions of Ammonia Nitrogen Removal Agents

→Hazards of Ammonia Nitrogen

Causes water eutrophication

Toxic to aquatic organisms

Increases difficulty and cost of subsequent treatment

Removal Principles

Chemical Precipitation: Forms insoluble precipitates
√ Oxidation Decomposition: Converts ammonia nitrogen to nitrogen gas
√ Ion Exchange: Uses special resin adsorption
√ Biological Transformation: Assists biological treatment processes

→Key Performance Indicators

√ Removal efficiency (typically >95%)

√ Reaction speed (5-30 minutes)

√ Sludge production

√ Risk of secondary pollution

 

2. Main Types of Ammonia Nitrogen Removal Agents & Characteristics

Type Representative Components pH Range Removal Rate Advantages Disadvantages
Chlorine-Based NaClO, ClO₂ 6-9 90-98% Fast reaction, low cost Produces chloramine byproducts
Persulfate-Based K₂S₂O₈ 3-11 85-95% Wide adaptability, no residue Requires catalysts
Magnesium Salt Composite MgCl₂+Na₂HPO₄ 8-10 95-99% Low sludge, recyclable Higher cost
Bio-Enhanced Nitrifying bacteria 6-8 70-90% Environmentally friendly Slow effect
Molecular Sieve Zeolite materials 4-10 80-92% Regenerable Small treatment capacity

 

3. Selection Guide for Different Applications

→Municipal Wastewater Treatment

√ Recommended Agents: Chlorine-based + bio-enhanced combination

√ Typical Parameters: Dosage 50-100mg/L

√ Precautions: Control residual chlorine <0.5mg/L

→Electroplating Industry Wastewater

√ Preferred Solution: Persulfate oxidation system

√ Special Requirements: Needs heavy metal capturing agents

√ Case Data: Reduces ammonia nitrogen from 150mg/L to 5mg/L

→ Livestock Wastewater Treatment

√ Best Choice: Magnesium salt composite precipitant

√ Process Key: Adjust pH to ~9

√ Cost-Effectiveness: ~$0.3-0.45 per ton

→Landfill Leachate

√ Solution: Molecular sieve pretreatment + advanced oxidation

√ Technical Challenge: Treats high-concentration ammonia nitrogen (>1000mg/L)

√ Innovative Approach: Catalytic oxidation technology

 

4. Usage Tips & Common Issues

→Best Practices

√ Lab Testing First: Conduct jar tests

√ Staged Dosing: Better results with 2-3 separate doses

√ Parameter Monitoring: Real-time ORP and pH monitoring

→Troubleshooting

√ Issue 1: Sudden efficiency drop

      -Possible Causes: Water quality change or agent failure

      -Solution: Retest to determine new dosage

√ Issue 2: Excessive foam

      -Solution: Add defoamer or reduce mixing intensity

→Safety Precautions

Wear protective equipment

Avoid mixing with acids

Store in cool, dry place

 

5. Future Development Trends

√ Green Formulations: Eco-friendly agent development

√ Smart Dosing: AI-based automatic control systems

√ Resource Recovery: Nitrogen/phosphorus recovery from wastewater

√ Hybrid Technologies: Physicochemical-biological combined processes

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